酸改性CoPd/TiO2催化CH4-CO2直接合成C2含氧化合物

采用酸处理方法对CoPd/TiO₂催化剂进行改性，并将酸改性催化剂用于温和条件下CH₄-CO₂梯阶转化直接合成C₂含氧化合物（乙酸和乙醇）的反应。在150～300℃考察了浸酸方式和不同种类酸处理对催化剂活性和选择性的影响。采用X射线衍射（XRD）、X射线光电子能谱（XPS）、NH₃程序升温脱附（NH₃-TPD）和N₂吸附对催化剂进行了表征。结果表明，酸改性明显提高了CoPd/TiO₂上C₂含氧化合物的生成速率和选择性。浸酸方式对催化剂性能和结构有显著影响，先用酸浸渍载体然后再浸渍活性金属所得催化剂具有更高的活性。在H₃PO₄、HNO₃和HCl中，H₃PO₄浸渍的催化剂活性最佳，在150℃时C₂含氧化合物（乙酸和乙醇）的生成速率为3365 μg/(g·h)，选择性达到91%。     

On the prediction of solubility of alkane in carbon dioxide using the LSSVM algorithm

The increasing global energy demand and declination of oil reservoir in recent years cause the researchers attention focus on the enhancement of oil recovery approaches. One of the extensive applicable methods for enhancement of oil recovery, which has great efficiency and environmental benefits, is carbon dioxide injection. The CO₂ injection has various effects on the reservoir fluid, which causes enhancement of recovery. One of these effects is extraction of lighter components of crude oil, which straightly depends on solubility of hydrocarbons in carbon dioxide. In order to better understand of this parameter, in this study, Least squares support vector machine (LSSVM) algorithm was developed as a novel predictive tool to estimate solubility of alkane in CO₂ as function of carbon number of alkane, carbon dioxide density, pressure, and temperature. The predicting model outputs were compared with the extracted experimental solubility from literature statistically and graphically. The comparison showed the great ability and high accuracy of developed model in prediction of solubility.     

超高强韧油井管合金设计与高强韧机制

 为了揭示1 000 MPa级低碳加铌钒钛微合金钢的高强韧机制,研究了S1(w(C)=0.09%)与S2(w(C)=0.17%)两种合金成分的油井管钢成分-工艺-组织-性能关系。试验表明,两种成分试验钢经水淬后的组织分别为板条贝氏体加少量马氏体和马氏体加少量贝氏体的复相组织。两种成分钢经过450~600 ℃、30 min的中温回火后,组织中均出现碳化物析出,且S1试验钢回火后的屈服强度基本不变,抗拉强度下降了约70 MPa,S2试验钢回火后的屈服强度与抗拉强度迅速升高170 MPa左右。溶度积公式的计算结果表明,两种钢的水淬组织中铌、钛元素析出彻底且析出物的体积分数都很小,因此回火铁素体基体中的VC析出强化对S1试验钢回火后屈服强度保持不变以及S2试验钢回火后屈服、抗拉强度提高起到重要作用。     

The effect of atmospheric plasma treatment of recycled carbon fiber at different plasma powers on recycled carbon fiber and its polypropylene composites

To increase the mechanical properties of recycled carbon fiber-reinforced polypropylene (PP) composites, recycled carbon fibers (RCF) were subjected to atmospheric plasma treatment at different plasma powers (100, 200, and 300 W). The changes on surface topography and roughness of RCF were examined by atomic force microscopy. Plasma treatment of RCF increased the roughness value of RCF. The variation of surface elemental compositions and tensile strength of RCF were determined by using X-ray photoelectron spectroscopy and tensile test, respectively. Plasma-treated RCF-reinforced PP composites were fabricated using high speed thermo-kinetic mixer. Plasma treatment of RCF at 100 W increased the tensile and flexural strength values of RCF-reinforced PP composites considerably by 17 and 11%, respectively. However, plasma treatment of RCF at higher plasma powers (200 W and 300 W) decreased tensile and flexural strength values of composites because of the etching of RCF. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47131.